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CAS Number 1313-59-3
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Linear Formula Na2O
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Molecular Weight 61.98
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MDL number MFCD00046201
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PubChem Substance ID 24883391
Sodium oxide is a chemical compound with the formula Na2O. It is used in ceramics and glasses, though not in a raw form. It is the base anhydride of sodium hydroxide, so when water is
added to sodium oxide NaOH is produced.
Na2O + H2O
→ 2 NaOH
Detailed Description:
The alkali metal oxides M2O
(M = Li, Na, K, Rb) crystallise in the antifluorite structure. In this motif
the positions of the anions and cations are reversed relative to their positions
in CaF2, with sodium ions tetrahedrally coordinated to
4 oxide ions and oxide cubically coordinated to 8 sodium ions.
Applications
Glass making
Sodium oxide is a significant component of glasses
and windows although it is added in the form of "soda" (sodium carbonate). Sodium oxide does
not explicitly exist in glasses, since glasses are complex cross-linked
polymers. Typically, manufactured glass contains around 15%
sodium oxide, 70% silica (silicon dioxide) and 9% lime (calcium oxide). The sodium
carbonate "soda" serves as a flux to lower the temperature at which
the silica melts. Soda glass has a much lower melting temperature than pure
silica, and has slightly higher elasticity. These changes arise because the
silicon dioxide and soda react to form sodium silicates of the general formula
Na2[SiO2]x[SiO3].
Na2CO3 → Na2O + CO2
Na2O +
SiO2 → Na2SiO3
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