CAS Number 57-11-4
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Linear Formula CH3(CH2)16COOH
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Molecular Weight 284.48
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Beilstein Registry Number 608585
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EC Number 200-313-4
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MDL number MFCD00002752
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PubChem Substance ID 24899616
Stearic acid is a saturated fatty acid with an 18-carbon chain and has the IUPAC name octadecanoic acid. It is a waxy solid and its chemical formula
is C17H35CO2H.
Detailed Description:
Its name comes from the Greek word στέαρ "stéar", which
means tallow.
The salts and esters of stearic acid are called stearates. As its ester, stearic acid is one of the most
common saturated fatty acids found in nature following palmitic acid.[9] The triglyceride derived from three molecules
of stearic acid is called stearin.
Uses
In general, the applications of stearic acid exploit
its bifunctional character, with a polar head group that can be attached to
metal cations and a nonpolar chain that confers solubility in organic solvents.
The combination leads to uses as a surfactant and softening agent. Stearic acid
undergoes the typical reactions of saturated carboxylic acids, a notable one
being reduction to stearyl alcohol, and esterification with a
range of alcohols. This is used in a large range of manufactures, from simple
to complex electronic devices.
Soaps, cosmetics, detergents
Stearic acid is mainly used in the production of
detergents, soaps, and cosmetics such as shampoos and shaving cream products. Soaps are
not made directly from stearic acid, but indirectly by saponification of triglycerides consisting of stearic
acid esters. Esters of stearic acid with ethylene glycol, glycol stearate, and glycol distearate are used to produce
a pearly effect in shampoos, soaps, and other cosmetic products. They are added
to the product in molten form and allowed to crystallize under controlled
conditions. Detergents are obtained from amides and quaternary alkylammonium
derivatives of stearic acid.
Lubricants, softening and release agents
In view of the soft texture of the sodium salt,
which is the main component of soap, other salts are also useful for their
lubricating properties. Lithium stearate is an important
component of grease. The stearate salts
of zinc, calcium, cadmium, and lead are used to soften PVC. Stearic acid is used along with castor oil for preparing
softeners in textile sizing. They are heated and mixed with caustic potash or
caustic soda. Related salts are also commonly used as release agents, e.g. in the
production of automobile tires.
Niche uses
Being inexpensively available and chemically benign,
stearic acid finds many niche applications, for example, in making plaster
castings from a plaster piece
mold or waste mold and in making the mold from a
shellacked clay original. In this use, powdered stearic acid is mixed in water
and the suspension is brushed onto the surface to be parted after casting. This
reacts with the calcium in the plaster to form a thin layer of calcium stearate, which functions as
a release agent. When reacted with zinc it forms zinc stearate, which is used as a
lubricant for playing cards (fanning powder) to ensure a smooth
motion when fanning. In compressed confections, it is used as a
lubricant to keep the tablet from sticking to the die.
Stearic acid is also used as a negative plate
additive in the manufacture of lead-acid batteries. It is added at the rate of
0.6 g per kg of the oxide while preparing the paste.[11] It is believed to
enhance the hydrophobicity of the negative plate, particularly during
dry-charging process. It also reduces the extension of oxidation of the freshly
formed lead (negative active material) when the plates are kept for drying in
the open atmosphere after the process of tank formation. As a consequence, the
charging time of a dry uncharged battery during initial filling and charging
(IFC) is comparatively lower, as compared to a battery assembled with plates
which do not contain stearic acid additive.
Fatty acids are classic components of candle-making. Stearic acid is used along with simple sugar or corn syrup as a hardener in candies.
Stearic acid is used to produce dietary supplements.
In fireworks, stearic acid is
often used to coat metal powders such as aluminium and iron. This prevents oxidation, allowing
compositions to be stored for a longer period of time.
Stearic acid is a common lubricant during injection molding and pressing of ceramic powders.[12] It is also used as a
mold release for foam latex that is baked in
stone molds.
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1-Heptadecanecarboxylic acid, C18:0, Cetylacetic acid, NSC 25956, NSC 261168, Octadecanoic acid, Stearophanic acid Stearic acid
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