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CAS Number 39365-88-3
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Linear Formula (l*K₂S)(m*K₂Sx)(n*K₂S₂O₃)
Potassium sulfide is the inorganic compound with the formula K2S. The colourless solid is
rarely encountered, because it reacts readily with water, a reaction that
affords potassium hydrosulfide (KSH) and potassium hydroxide (KOH).
Detailed description
Most commonly, the term potassium sulfide
refers loosely to this mixture, not the anhydrous solid.
Structure
It adopts "antifluorite structure," which
means that the small K+ ions
occupy the tetrahedral (F−) sites in fluorite, and the larger S2−centers
occupy the eight-coordinate sites. Li2S, Na2S, and Rb2S
crystallize similarly.
Use in fireworks
Potassium sulfides are formed when black powder is burned and are
important intermediates in many pyrotechnic effects, such as senko hanabi and
some glitter formulations.
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