Saturday 7 October 2017

TOLUENE OR TOLUOL



anhydrous, 99.8%
·         CAS Number 108-88-3

·         Linear Formula C6H5CH3

·         Molecular Weight 92.14

·          Beilstein Registry Number 635760
·          EC Number 203-625-9

·          MDL number MFCD00008512

·          PubChem Substance ID 57648083

·          eCl@ss 39011102

Properties

Related Categories
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grade  
anhydrous
vapor density  
3.2 (vs air)
vapor pressure  
22 mmHg ( 20 °C)

26 mmHg ( 25 °C)
InChI Key  
YXFVVABEGXRONW-UHFFFAOYSA-N
assay  
99.8%
form  
liquid

Toluene  also known as toluol  is a colorless, water-insoluble liquid with the smell associated with paint thinners. It is a mono-substituted benzene derivative, consisting of a CH3 group attached to a phenyl group. As such, its IUPAC systematic name is methylbenzene. It is an aromatic hydrocarbon.
Detailed description
Toluene is widely used as an industrial feedstock and a solvent.[6] In 2013, worldwide sales of toluene amounted to about 24.5 billion US-dollars.[7]
As the solvent in some types of paint thinner, contact cement and model airplane glue, toluene is sometimes used as a recreational inhalant[8] and has the potential of causing severe neurological harm.

Production

Toluene occurs naturally at low levels in crude oil and is a byproduct in the production of gasoline by a catalytic reformer or ethylenecracker; It is also a byproduct of the production of coke from coal. Final separation and purification is done by any of the distillation or solvent extraction processes used for BTX aromatics (benzene, toluene, and xylene isomers).

Laboratory preparation

Toluene is so inexpensively produced industrially that it is not prepared in the laboratory. In principle it could be prepared by a variety of methods. For example, although only of didactical interest, benzene reacts with methyl chloride in presence of a Lewis acid such as aluminium chloride to give toluene:
C6H5H + CH3Cl → C6H5CH3 + HCl
Such reactions are complicated by polymethylation because toluene is more susceptible to alkylation than is benzene.

Uses

Toluene is mainly used as a precursor to benzene via hydrodealkylation:
C6H5CH3 + H2 → C6H6 + CH4
The second ranked application involves its disproportionation to a mixture of benzene and xylene. When oxidized it yields benzaldehyde and benzoic acid, two important intermediates in chemistry.[20]

Precursor to other chemicals

In addition to the synthesis of benzene and xylene, toluene is a feedstock for toluene diisocyanate (used in the manufacture of polyurethane foam), trinitrotoluene (the explosive, TNT), and a number of synthetic drugs.

Solvent

Toluene is a common solvent, e.g. for paints, paint thinners, silicone sealants,[21] many chemical reactants, rubber, printing ink, adhesives (glues), lacquers, leather tanners, and disinfectants.

Fuel

Toluene can be used as an octane booster in gasoline fuels for internal combustion engines. Toluene at 86% by volume fueled all the turbo Formula One teams in the 1980s, first pioneered by the Honda team. The remaining 14% was a "filler" of n-heptane, to reduce the octane to meet Formula One fuel restrictions. Toluene at 100% can be used as a fuel for both two-stroke and four-stroke engines; however, due to the density of the fuel and other factors, the fuel does not vaporize easily unless preheated to 70 °C (158 °F). Honda solved this problem in their Formula One cars by routing the fuel lines through the exhaust system to heat the fuel.
In Australia in 2003, toluene was found to have been illegally combined with petrol in fuel outlets for sale as standard vehicular fuel. Toluene incurs no fuel excise tax, while other fuels are taxed at more than 40%, providing a greater profit margin for fuel suppliers. The extent of toluene substitution has not been determined.
Toluene is one of a group of fuels that have recently included in jet fuel surrogate blends.[24] Toluene is used as a jet fuel surrogate for its content of aromatic compounds.

Niche applications

In the laboratory, toluene is used as a solvent for carbon nanomaterials, including nanotubes and fullerenes, and it can also be used as a fullerene indicator. The color of the toluene solution of C60 is bright purple. Toluene is used as a cement for fine polystyrene kits (by dissolving and then fusing surfaces) as it can be applied very precisely by brush and contains none of the bulk of an adhesive. Toluene can be used to break open red blood cells in order to extract hemoglobin in biochemistry experiments. Toluene has also been used as a coolant for its good heat transfer capabilities in sodium cold traps used in nuclear reactor system loops. Toluene had also been used in the process of removing the cocaine from coca leaves in the production of Coca-Cola syrup.

Packaging

1, 6×1, 2, 4×2 L in Sure/Seal™
18 L in Pure-Pac™ 1
20 L in Pure-Pac™ 2
200 L in Kilo-Lab™
200 L in Pure-Pac™ 1
56 L in Pure-Pac™ 1
100, 12×100 mL in Sure/Seal™
400 L in Kilo-Lab™

PRICE

$140.95/KG OR $64.06/IB

For more information:

mobile: +2348039721941

contact person: emeaba uche

e-mail: emeabau@yahoo.com




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